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物理化学学报  2006, Vol. 22 Issue (04): 441-444    DOI: 10.1016/S1872-1508(06)60015-6
研究论文     
颜色指示法高通量筛选多相催化材料
孙波;孟祥举;王世超;孙淑清;肖丰收
吉林大学化学学院, 无机合成与制备国家重点实验室, 长春 130023; 天津大学理学院化学系, 天津 300072; 吉林化工学院药物化学系, 吉林 132022
High-throughput Color-screening of Heterogeneous Catalysts
SUN Bo;MENG Xiang-Ju;WANG Shi-Chao;SUN Shu-Qing;XIAO Feng-Shou
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China; Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, P. R.China; Department of Chemistry, Jilin Institute of Chemical Technology, Jilin 132022, P. R.China
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摘要： 介绍一种简单的组合化学技术, 用来筛选或优化多相催化反应中的催化剂. 在酯化反应中, 用甲基橙指示剂指示酯化反应的进程并对沸石的类型, 不同碳链的醇和酸的催化活性进行研究. 在光催化反应中, 选择甲基橙、罗丹明B作为反应物. 通过颜色变化, 对不同方法制备的TiO2进行高通量筛选.
关键词： 高通量筛选;  组合化学;  多相催化剂;  颜色指示剂;  光催化反应    
Abstract: A high-throughput method has been developed for screening and optimization of heterogeneous catalysts and reacting condition by judging from the change in color of reactants and products as well as indicators during reaction. As compared with other techniques, this method is simple and viable. In catalytic esterification, methyl orange is chosen as an indicator for screening the activities under various conditions. In the photocatalytic degradation of dyes, methyl orange and Rhodamine B are chosen as indicators for the catalytic reactions. Furthermore, the results obtained from high-throughput color-screening have been verified by GC and UV-Vis spectrometer, showing a good accordance between the color-screening and the GC, UV-Vis techniques.
Key words: High-throughput screening    Combinatorial chemistry    Heterogeneous catalysts    Color indicator    Photocatalystic reaction
收稿日期: 2005-09-29 出版日期: 2006-04-10
通讯作者: 肖丰收     E-mail: fsxiao@mail.jlu.edu.cn
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引用本文:

孙波;孟祥举;王世超;孙淑清;肖丰收. 颜色指示法高通量筛选多相催化材料[J]. 物理化学学报, 2006, 22(04): 441-444, 10.1016/S1872-1508(06)60015-6

SUN Bo;MENG Xiang-Ju;WANG Shi-Chao;SUN Shu-Qing;XIAO Feng-Shou. High-throughput Color-screening of Heterogeneous Catalysts. Acta Phys. -Chim. Sin., 2006, 22(04): 441-444, 10.1016/S1872-1508(06)60015-6.

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http://www.whxb.pku.edu.cn/CN/10.1016/S1872-1508(06)60015-6    或    http://www.whxb.pku.edu.cn/CN/Y2006/V22/I04/441

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