物理化学学报 >> 2006, Vol. 22 >> Issue (12): 1560-1562.doi: 10.1016/S1872-1508(06)60079-X

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N-甲基甲酰胺与醇的氢键相互作用

RAMACHANDRAN Krishnamurthy;DHARMALINGAM Kurunthu;SIVAGURUNATHAN Periyasamy   

  1. (Department of Physics, Annamalai University, Annamalai Nagar 608002, Tamil Nadu, India)
  • 收稿日期:2006-06-07 修回日期:2006-07-17 发布日期:2006-12-06
  • 通讯作者: SIVAGURUNATHAN Periyasamy E-mail:sivatamil2001@yahoo.com

Hydrogen Bonding Interaction between N-methylformamide and Alcohols

RAMACHANDRAN Krishnamurthy;DHARMALINGAM Kurunthu;SIVAGURUNATHAN Periyasamy   

  1. (Department of Physics, Annamalai University, Annamalai Nagar 608002, Tamil Nadu, India)
  • Received:2006-06-07 Revised:2006-07-17 Published:2006-12-06
  • Contact: SIVAGURUNATHAN Periyasamy E-mail:sivatamil2001@yahoo.com

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摘要： The hydrogen bonding interactions between N-methylformamide and primary, secondary, and tertiary alcohols have been studied using the FTIR spectroscopic method. The most likely association complex between alcohol and N-methylformamide is the 1:1 stoichiometric complex formed between the hydroxyl group of alcohol and the carbonyl group of N-methylformamide. The formation constant of the 1:1 complexes has been calculated using the Nash method. It appears that the primary alcohols have larger formation constant compared with the secondary and tertiary alcohols. The results showed that the proton-donating ability of the alcohols decreased in the order: primary>secondary>tertiary, and that the association constant increased with the increase in carbon chain of the alkyl group of alcohols.

关键词: FTIR spectroscopy, Hydrogen bond, Alcohol

Abstract: The hydrogen bonding interactions between N-methylformamide and primary, secondary, and tertiary alcohols have been studied using the FTIR spectroscopic method. The most likely association complex between alcohol and N-methylformamide is the 1:1 stoichiometric complex formed between the hydroxyl group of alcohol and the carbonyl group of N-methylformamide. The formation constant of the 1:1 complexes has been calculated using the Nash method. It appears that the primary alcohols have larger formation constant compared with the secondary and tertiary alcohols. The results showed that the proton-donating ability of the alcohols decreased in the order: primary>secondary>tertiary, and that the association constant increased with the increase in carbon chain of the alkyl group of alcohols.

Key words: FTIR spectroscopy, Hydrogen bond, Alcohol