物理化学学报 >> 2008, Vol. 24 >> Issue (06): 987-991.doi: 10.1016/S1872-1508(08)60044-3

研究论文 上一篇    下一篇

不同温度下脯氨酸在非水阴离子、阳离子及非离子型表面活性剂中的相互作用

ALI Anwar; SHAHJAHAN   

  1. Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi-110 025, India
  • 收稿日期:2008-01-04 修回日期:2008-02-22 发布日期:2008-06-03
  • 通讯作者: ALI Anwar E-mail:Email: anwar_jmi@yahoo.co.in

Interactions of Proline in Non-aqueous Anionic, Cationic and Nonionic Surfactants at Different Temperatures

ALI Anwar; SHAHJAHAN   

  1. Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi-110 025, India
  • Received:2008-01-04 Revised:2008-02-22 Published:2008-06-03
  • Contact: ALI Anwar E-mail:Email: anwar_jmi@yahoo.co.in

摘要: Density and viscosity data of proline (Pro) in sodium dodecyl sulfate/cetyltrimethylammonium bromide/poly (oxyethylene) isooctyl phenyl ether in formamide were measured at 298.15, 303.15, 308.15, and 313.15 K and 0.1 MPa. The density data were utilized to evaluate standard partial molar volumes (φ0 v) and partial molar isobaric expansibility (φ0 E). The viscosity data were used to evaluate A-and B-coefficients, free energy of activation of viscous flow (⊿μ0*1 ) and (⊿μ0*2 ), per mole of solvent and solute respectively, enthalpy (⊿H*) and entropy (⊿utilized in the qualitative elucidation of the Pro-surfactant/formamide and Pro-Pro interactions in the present systems.

关键词: Partial molar volume, Viscosity coefficient, Interaction

Abstract: Density and viscosity data of proline (Pro) in sodium dodecyl sulfate/cetyltrimethylammonium bromide/poly (oxyethylene) isooctyl phenyl ether in formamide were measured at 298.15, 303.15, 308.15, and 313.15 K and 0.1 MPa. The density data were utilized to evaluate standard partial molar volumes (φ0 v) and partial molar isobaric expansibility (φ0 E). The viscosity data were used to evaluate A-and B-coefficients, free energy of activation of viscous flow (⊿μ0*1 ) and (⊿μ0*2 ), per mole of solvent and solute respectively, enthalpy (⊿H*) and entropy (⊿utilized in the qualitative elucidation of the Pro-surfactant/formamide and Pro-Pro interactions in the present systems.

Key words: Partial molar volume, Viscosity coefficient, Interaction

MSC2000: 

  • O642