物理化学学报 >> 1985, Vol. 1 >> Issue (02): 200 -204 .doi: 10.3866/PKU.WHXB19850213
Zhang Zhilian; Dai Xinhe
Abstract: The surface morphology,crystallite size distribution, and the surface and depth analyses for the coneentratons of impurity elements and cobalt oxide ions of several samples of Co_3O_4 catalyst for ammonia oxidation, which were obtained under various conditions for preparation, calination,usage,and regeneration, were observed by means of a transmission electron microscopy(TEM), a scanning electron microscopy(SEM),and an ion microprobe mass analyzer (IMMA). The observed results are discussed in relating with the experimental activity of the catalyt. It is concluded that the possible causes of the decline in the activity of the catalyst are that the impurity elements transport from the bulk phase and enrich onto the surface and the cobalt oxide ions on the surface decrease when the catalyst has been used at the high temperature for a long time.
张知廉;戴新鹤. 氨氧化钴催化剂的表面研究[J]. 物理化学学报, 1985, 1(02): 200 -204 .
Zhang Zhilian; Dai Xinhe. SURFACE RESEARCH OF COBALT CATALYSTS FOR OXIDATION OF AMMONIA[J]. Acta Phys. -Chim. Sin., 1985, 1(02): 200 -204 .
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