物理化学学报 >> 1987, Vol. 3 >> Issue (01): 92-96.doi: 10.3866/PKU.WHXB19870117
DISSOCIATION OF ETHYLENE OXIDE ON A SILVER WIRE
Abstract: Ethylene oxde is catalytically dissociated on silver surface. The first step of this reaction is to isomerize to acetyl aldehyde. The single collision catalytic di- ssociation probability is several orders of magnitude higher than the unimolecular reaction probability calculated by RRKM theory. Its activation energy decresese from 238 kJ mol~(-1) TO 42.6 kJ mol~(-1). The reaction order, reaction mechanism and product yield of this reaction are also described. These results will be helpful for the production of ethylene in industrial scale.
袁伟. 银丝上环氧乙烷分解反应的研究[J]. 物理化学学报, 1987, 3(01): 92-96.
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