物理化学学报 >> 1987, Vol. 3 >> Issue (04): 430-434.doi: 10.3866/PKU.WHXB19870418

研究简报 上一篇    下一篇

1,1’-三亚甲基双环戊二烯基-特丁基镧四氢呋喃配合物的13C核磁共振化学位移研究

游效曾; 吴伟雄; 李邨; 李重德; 钱长涛   

  1. 南京大学配位化学研究所; 中国科学院上海有机化学研究所
  • 收稿日期:1986-01-19 修回日期:1986-07-15 发布日期:1987-08-15

STUDY OF THE 13C NMR CHEMICAL SHIFT ON THE THF-COORDINATED (1,1'-TRIME-THYLENEDICYCLOPENTADIENYL) (TERT-BUTYL) LANTHANIDE COMPLEX

You Xiaozeng; Wu Weixiong; Li Cun; Li Chongde; Qian Changtao   

  1. Coordination Chemistry Institute; Nanjing University
    Shanghai Institute of Organic Chemistry; Academia Sinica
  • Received:1986-01-19 Revised:1986-07-15 Published:1987-08-15

PDF

2004

赞

Abstract: We have synthesized the THF-coordinated(1,1′-Trimethylenedicyclopentadienyl) (tert-butyl) lanthanide complex. The ~(13)C NMR spectrum in tetrahydrofuran-d_8 so- lution has been determined and assigned. A theoritical calculation of ~(13)C NMR che- mical shift based on our INDO/σ program has been applied to this compound as the first calculation for lanthanide complex which included f orbitals. The corela- tion between the theoretical calculation results and the experimental data is sati- sfactory.