物理化学学报 >> 1987, Vol. 3 >> Issue (05): 529-533.doi: 10.3866/PKU.WHXB19870516

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ATP与Mg2+、Ca2+生成配合物反应的热力学研究

刘云娜   

  1. 中国科学院化学研究所, 北京
  • 收稿日期:1986-04-01 修回日期:1986-10-28 发布日期:1987-10-15

THERMODYNAMIC STUDIES OF THE FORMATION FOR ADENOSINE TRIPHOSPHATE COMPLEXES WITH MAGNESIUM ION AND CALCIUM ION

Liu Yunna   

  1. Institute of Chemistry; Academia Sinica; Beijing
  • Received:1986-04-01 Revised:1986-10-28 Published:1987-10-15

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Abstract:

The formation constant (K) and thermodynamic parameters (ΔC.ΔH.ΔS) in reactions in which complexes of adenosine triphosphate with magnesium ion and calcium ion are formed have been obtained by a microcalorimetric method.
All experimentes were made at 30 ℃, pH=8.0 and at ionic strength μ=0.2 mol L~(-1). Measured experimental values indicate that complex formation reactions are driven by the entropic factor.