物理化学学报 >> 1988, Vol. 4 >> Issue (03): 325-328.doi: 10.3866/PKU.WHXB19880319
李学初; Jackson; W.M.
Abstract: The vibrational distributions of CNX~2Σ~+ have been obtained in photolysis of BrCN at 193 nm. An obvious increase of v″=1 population was found with increasing the collision of CN and BrCN. The populations in the v″=2—5 also appeared after the tens collisions. The case can not be found in photolysis of ClCN. A possible explanation was suggested that the CN radical is excited vibrationally due to a recoil which occurs at the collision of CN X~2Σ~+, v″=0 radical carrying 1.5 eV energy with the heavy molecule BrCN. This is similar to the vibrational excitation of CO at collision with a high speed H atom.
李学初;Jackson;W.M.. 高平动能(1.15 eV)CN基的T-V过程的探讨[J]. 物理化学学报, 1988, 4(03): 325-328.
Li Xuechu*;W.M.Jackson. DISCUSSION ON THE T-V PROCESS IN CN RADICAL WITH HIGH TRANSLATION ENERGY (1.5 eV)[J]. Acta Phys. -Chim. Sin., 1988, 4(03): 325-328.
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