物理化学学报 >> 1988, Vol. 4 >> Issue (04): 436-440.doi: 10.3866/PKU.WHXB19880423
Abstract: Propylene oxide catalytically dissociates at the silver wire. The first-step product of this reaction is not acetone, but propyl aldehyde. According to the new assumptions suggested, the reaction probability per encounter has been simulated by p_m=∫~∞_(E_0) 1/(kT) e~(-E/kT)dE/∫~∞_(E_d) 1/(kT)e~(-E/kT)dEand a satisfactory result has been achieved in both qualitative and quantitative aspects. The energy transfer efficiency at gas-solid surface and the essence of catalytic action have also been reviewed concisely.
袁伟. 银丝上环氧丙烷分解反应的研究[J]. 物理化学学报, 1988, 4(04): 436-440.
Yuan Wei. STUDY OF DISSOCIATION OF PROPYLENE OXIDE AT A SILVER WIRE[J]. Acta Phys. -Chim. Sin., 1988, 4(04): 436-440.
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