物理化学学报 >> 1990, Vol. 6 >> Issue (02): 215-219.doi: 10.3866/PKU.WHXB19900216
研究简报 上一篇 下一篇
吴雄武; 陈智; 滕藤; 宁永成
收稿日期:
修回日期:
发布日期:
通讯作者:
Wu Xiong-Wu; Chen Zhi; Teng Teng; Ning Yong-Cheng
Received:
Revised:
Published:
Contact:
Abstract: The interaction of water with solvents in H_2O-TBP-CCl_4 system and H_2O-p-dio-xan-CCl_4 system is studied with IR method. The absorbances of free water, 1:1 and 1:2 complex are observed and the absorbance frequencies of each species are assigned. In H_2O-TBP-CCl_4 system, there exists not only symmetric 1:2 complex but also unsymmetric one. The water molecule in unsymmetric 1:2 complex is considered to be hydrogen bonded with two kinds of oxygen atom in TBP. And the hydrogen bonds are different in strenghth. Because of diffeent spatial configurations of solvent molecules around water, more than one kind of 1:2 complex exist in H_2O-p-dioxan-CCl_4 system.
吴雄武;陈智;滕藤;宁永成. 水与受质子溶剂氢键作用的IR研究[J]. 物理化学学报, 1990, 6(02): 215-219.
Wu Xiong-Wu; Chen Zhi; Teng Teng; Ning Yong-Cheng. IR Study of the Interaction of Water with Proton-Accepting Solvents[J]. Acta Phys. -Chim. Sin., 1990, 6(02): 215-219.
0 /
导出引用管理器 EndNote (中文内容)|EndNote (英文内容)| Reference Manager|ProCite|BibTeX|RefWorks
链接本文: http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19900216
http://www.whxb.pku.edu.cn/CN/Y1990/V6/I02/215
Cited