物理化学学报 >> 1990, Vol. 6 >> Issue (06): 739-742.doi: 10.3866/PKU.WHXB19900620
He Ming-Qian; Fu Xiang-Kai
Abstract: From superacid POSA (perfluorooctanesulfonic acid) catalyzed esterification of p-substituted benzoic acids with ethanol, we got not only the rate canstants k, the energy of activation ΔE, the entropy of activation ΔS~≠, and the enthalpy of acti-vation ΔH~≠; but also a good Hammett linear Free energy relationship (LFE Rela-tionship). This is the first report of applying LFE relationship to superacid catalysis. Finally, the reaction intermediate, the reaction constant ρ, and the mechanism of the reaction were also discussed. It is deduced by this paper that the mechanism of POSA catalyzed esterification is basically identical with those of normal strong acids catalysis, and the reaction is a process of general acid catalysis.
贺明谦;傅相锴. 超酸POSA催化酯化反应动力学及线性自由能关系[J]. 物理化学学报, 1990, 6(06): 739-742.
He Ming-Qian; Fu Xiang-Kai. RESEARCH ON KINETICS AND LFE RELATIONSHIP OF SUPERACID POSA CATALYZED ESTERIFICATION[J]. Acta Phys. -Chim. Sin., 1990, 6(06): 739-742.
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