物理化学学报 >> 1991, Vol. 7 >> Issue (02): 219-222.doi: 10.3866/PKU.WHXB19910218

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苯基重氮盐-冠醚分子嵌合物的FAB-MS及其准分子离子生成机理的研究

卞则樑; 张启元; 孙祥玉; 赵瑶兴   

  1. 中国科学院化学研究所、北京大学化学系北京分子动态及稳态结构国家实验室，北京 100080；中国科学院研究生院，北京
  • 收稿日期:1989-11-28 修回日期:1990-06-05 发布日期:1991-04-15
  • 通讯作者: 卞则樑

Investigation of Fast Atom Bombardment Mass Spectrometry of Arenediazonium Salts/Mechanism of Their Quasi-Molecular Ions

Bian Ze-Liang; Zhang Qi-Yuan; Sun Xiang-Yu; Zhao Yao-Xing   

  1. National Laboratory for Structural Chemistry of University and State Species, Beijing 100080; Institute of Chemistry, Academia Sinica, Beijing
  • Received:1989-11-28 Revised:1990-06-05 Published:1991-04-15
  • Contact: Bian Ze-Liang

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关键词: 苯基重氮盐, 冠醚分子嵌合物, FAB-MS

Abstract: Fast atom bombardment mass spectra of a series of arenediazonium salts with various substituents complexed with 18-crown-6 and dibenzo-24-crown-8 ethers were examined. The correlation between quasi-molecular ion abundance of various complexes and the properties, coordination ability of donor-acceptor linkages in the complexes were studied. By using molecular orbital calculation we have successfully demonstrated that the correlation cited is related to the electron cloud densities on the heteroatoms α-N and β-N of arenediazonium salts.

Key words: Arenediazonium salts, Crown ethers complexs, Fast atom bombardment mass spectrometry