物理化学学报 >> 1991, Vol. 7 >> Issue (04): 480-484.doi: 10.3866/PKU.WHXB19910420

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非水溶液盐效应的气液色谱研究——非电解质(烃、芳烃、氯代烃、酮)+盐(Nal、NaSCN、KSCN)+碳酸丙烯酯体系

白同春; 王健吉; 刘文彬; 卢锦梭   

  1. 河南师范大学化学系，新乡 453002
  • 收稿日期:1990-04-24 修回日期:1990-11-10 发布日期:1991-08-15
  • 通讯作者: 白同春

Study on the Salt Effect in Nonaqueous Solutions by Gas Liquid Chromatography——For Nonelectrolyte Solute (Hydrocarbons,Aromatic Hydrocarbons,Chloro-Hydrocarbons,Ketones) in Salt (Nal, NaSCN, KSCN) and Propy-Lene Carbonate Solutions

Bai Tong-Chun; Wang Jian-Ji; Liu Wen-Bin; Lu Jin-Suo   

  1. Chemistry Department of Henan Normal University, Xinxiang 453002
  • Received:1990-04-24 Revised:1990-11-10 Published:1991-08-15
  • Contact: Bai Tong-Chun

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关键词: 气液色谱, 非水溶液, 盐效应, 活度系数, 碳酸丙烯酯

Abstract: The gas-liquid chromatographic method was used to measure the activity coefficients at infinite dilution (γ_1~∞) of some nonelectrolyte solutes in salt containing solutions of propylene carbonate at 333.2 K. For examining the relationship between lgγ_1~∞ and salt concentrations, the salt effect coefficients of solutes were calculated, and the interactions of solute with salt were disscused. Furthermore, the equilibrium constant of complex interaction between chloroform with anions has been obtained.

Key words: Gas liquid chromatography, Nonaqueous solution, Salt effect, Activity coefficient, Propylene carbonate