物理化学学报 >> 1991, Vol. 7 >> Issue (05): 577-581.doi: 10.3866/PKU.WHXB19910512

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氧心羧桥异三核过渡金属簇合物[Fe2MO(CH3COO)6Py3].Py(1,M=Mn;2,M=Co;3,M=Ni)和[Fe2MO(CCl3COO)6(THF)3](4,M=Mn;5,M=Co;6,M=Ni)电子光谱的研究

余秀芬; 王哲民   

  1. 中国科学院福州结构化学开放研究实验室; 福州大学化学系, 福州 350002
  • 收稿日期:1990-04-10 修回日期:1990-08-15 发布日期:1991-10-15
  • 通讯作者: 余秀芬

OXO-Centered Heterotrinuclear Transition Metal Carboxylate Complexes Studies on the Electronic Spectra of[Fe2MO(CH3COO)6Py3].Py and [Fe2MO(CCl3COO)3(THF)3](M=Mn,Co,Ni)

Yu Xiu-Fen; Wang Zhe-Min   

  1. Fuzhou Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Academia Sinica; Department of Chemistry, Fuzhou Universtry, Fuzhou 350002


  • Received:1990-04-10 Revised:1990-08-15 Published:1991-10-15
  • Contact: Yu Xiu-Fen

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关键词: 电子光谱, 氧心羧桥簇合物

Abstract:

The UV/VIS spectra for pyridine solution of complexes [Fe_2MO(CH_3COO)_6Py_2]·Py and THF solution of complexes Fe_2MO(CCl_3COO)_6(THF)_3 were studied. The d-d transitions were assigned and the ligand field parameters(B,D_q,β) were calculated for the related metal ions according to ligand field theory (Tanabe-Sugano diagram) in terms of O_h symmetry and reasonably good fits were obtained for the calculated and observed frequencies. The calculated results show that (1) the larger the ionic potential for M~(2+) ion, the larger the values of B, D_q for Fe~(3+) ion (2) the ligand field parameters of metal ions vary in parallel with the electronagativity of R in RCOO~-.

Key words: Electronic spectra, Cluster, Carboxylate complex