物理化学学报 >> 1991, Vol. 7 >> Issue (05): 601-604.doi: 10.3866/PKU.WHXB19910517
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徐映宏; 邓郁
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Xu Ying-Hong; Deng Yu
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关键词: Thermokinetics; First order reaction; Thermograms pesk-heights method
Abstract:
In the previous articles~[1,2], a data processing method for studies on thermokinetics of a first order reaction in liquid phase had been developed. It was called the dimensionless parameter method, in which the dimensionless parameter and the rate constant of a reaction system were calculated from the thermogram's peak-area. In this paper in the light of a theoretical thermogram's equation of a first order reaction, a novel data processing method is proposed, in which the dimensionless parameter and the rate constant are calculated from the thermogram's peak-heights with-out using any peak-area. Thereby the problems arisen from the peak-area-computation can be avoided. In order to test the validity of this novel method, ...
Key words: Thermokinetics; First order reaction; Thermograms pesk-heights method
徐映宏;邓郁. 热动力学的研究 X. 一级反应的热谱峰高法[J]. 物理化学学报, 1991, 7(05): 601-604.
Xu Ying-Hong; Deng Yu. Studies on Thermokinetics X. Thermogram's Peak-Heights Method for First Order Reactions[J]. Acta Phys. -Chim. Sin., 1991, 7(05): 601-604.
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链接本文: http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19910517
http://www.whxb.pku.edu.cn/CN/Y1991/V7/I05/601
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