物理化学学报 >> 1992, Vol. 8 >> Issue (02): 232-235.doi: 10.3866/PKU.WHXB19920217
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张秋禹; 严宝珍; 郭洪猷; 王作新; 徐广智
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Zhang Qiu-Yu; Yan Bao-Zhen; Guo Hong-You; Wang Zuo-Xin; Xu Guang-Zhi
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关键词: 水解反应历程, 31P NMR, 硫代磷酸酯
Abstract: ~(31)P NMR spectra during the hydrolysis process of thiophosphate(A) ??? in neutral, acid and basic media were recorded. By analyzing the ~(31)P NMR date obtained, hydrolysis mechanism was confirmed. Information of hydrolysis rate in different media was also obtained. In addition, the solvent effects of ~(31)P NMR of thiophosphate were investigated in detail.
Key words: Hydrolysis mechanism, 31P NMR, Thiophosphate
张秋禹;严宝珍;郭洪猷;王作新;徐广智. 用31P NMR研究硫代磷酸酯水解反应历程[J]. 物理化学学报, 1992, 8(02): 232-235.
Zhang Qiu-Yu; Yan Bao-Zhen; Guo Hong-You; Wang Zuo-Xin; Xu Guang-Zhi. Studies on the Hydrolysis Mechanism of Thiophosphate by 31P NMR[J]. Acta Phys. -Chim. Sin., 1992, 8(02): 232-235.
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链接本文: http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19920217
http://www.whxb.pku.edu.cn/CN/Y1992/V8/I02/232
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