物理化学学报 >> 1992, Vol. 8 >> Issue (02): 274-278.doi: 10.3866/PKU.WHXB19920227
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詹明生; 周士康; 储焰南; 宋芳青; 杨新; 李方琳
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Zhan Ming-Sheng; Zhou Shi-Kang; Chu Yan-Nan; Song Fang-Qing; Yang Xin; Li Fang-Lin
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关键词: 交叉分子束, 化学发光, 二溴甲烷
Abstract: This paper reported an observation of the chemiluminescence in the 400~900 nm spectral region produced by the crossed molecular beam reaction of F(~2P) with CH_2Br_2, as well as the reaction mechanism. Under single collision condition, only vibrationally excited HF~≠(X,V) (V≤3) can be observed. In the case of multicollision, in addition to V≤3, HF~≠(X,V) with V>3 and electronically excited Br_2~*(B), BrF~*(B) have been detected. The equilibrium rotational temperature for HF(3,0) band is 320 K, and the relative population ratio of different V levels of HF is N_3:N_4:N_5=0.69:1.00:0.12.
Key words: Crossed molecular beam, Chemiluminescence, Dibromomethane
詹明生;周士康;储焰南;宋芳青;杨新;李方琳. F(2P)与CH2Br2反应的化学发光光谱及其动力学[J]. 物理化学学报, 1992, 8(02): 274-278.
Zhan Ming-Sheng; Zhou Shi-Kang; Chu Yan-Nan; Song Fang-Qing; Yang Xin; Li Fang-Lin. Chemiluminescence and Dynamics of the Reaction F(2P)+CH2Br2[J]. Acta Phys. -Chim. Sin., 1992, 8(02): 274-278.
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链接本文: http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19920227
http://www.whxb.pku.edu.cn/CN/Y1992/V8/I02/274
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