物理化学学报 >> 1992, Vol. 8 >> Issue (04): 530-535.doi: 10.3866/PKU.WHXB19920421

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Rh(acac)(CO)2的振动光谱及其简正坐标分析

刘省明; 林政炎; 殷元骐   

  1. 中国科学院福建物质结构研究所,结构化学开放实验室,福州 350002;中国科学院兰州化学物理研究所,兰州 730000
  • 收稿日期:1991-03-02 修回日期:1991-09-11 发布日期:1992-08-15
  • 通讯作者: 殷元骐

Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)2

Liu Sheng-Ming; Lin Zheng-Yan; Yin Yuan-Qi   

  1. Fuzhou Laboratory of Structural Chemistry, Academia Sinica, Fuzhou 350002; Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000
  • Received:1991-03-02 Revised:1991-09-11 Published:1992-08-15
  • Contact: Yin Yuan-Qi

关键词: 振动光谱, 红外, 拉曼, 简正坐标分析

Abstract: The Raman and infrared spectra of dicarbonyl (acetylacetonato) rhodium have been measured form 4000 to 80 cm~(-1). A normal coordinate analysis was performed for all modes by using Simplified General Valence Force Field. 38 force constants were used during the calculation process. Some new assignments of bands have been made and they were supported by some proofs. The reliabilty of result was discussed.

Key words: Vibrational spectrum, Infrared spectra, Raman spectra, Normal coordinate analysis