物理化学学报 >> 1992, Vol. 8 >> Issue (05): 707-711.doi: 10.3866/PKU.WHXB19920527

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支持电解质对无水甲醇电氧化途径的影响

周志华; 胡卫东; 卢文庆; 周益明; 薛宽宏   

  1. 南京师范大学化学系,南京 210024
  • 收稿日期:1991-07-09 修回日期:1992-01-28 发布日期:1992-10-15
  • 通讯作者: 周志华

Effect of Supporting Electrolyte on the Electrochemical Oxidation Pathways of Anhydrous Methanol at Gold Electrode

Zhou Zhi-Hua; Hu Wei-Dong; Lu Wen-Qing; Zhou Yi-Ming; Xue Kuan-Hong   

  1. Department of Chemistry, Nanjing Normal University, Nanjing 210024
  • Received:1991-07-09 Revised:1992-01-28 Published:1992-10-15
  • Contact: Zhou Zhi-Hua

关键词: 甲醇, 电氧化, 金电极, 原位博里叶红外光谱

Abstract: The electroxidation mechanism of methanol at gold electrode with different supporting electrolytes in anhydrous methanol was investigated using In situ FTIR spec-troscopy. It has been proved that the electroxidation pathway and products are different for different supporting electrolytes. When NaOH was used as supporting electrolyte, the electroxidation products are HCOOCH_3 and HCOO~- ion; moreover, the relative quantities of HCOOCH_3 and HCOO~- produced are affected by tbe concentration of NaOH. When NaClO_4 and TBABF_4 are used as supporting electrolyte, HCOOCH_3 and CH_3OCH_2OCH_3 will be the only products.

Key words: Methanol, Electroxidation, Gold electrode, In situ FTIR spectroscopy