物理化学学报 >> 1992, Vol. 8 >> Issue (06): 824-828.doi: 10.3866/PKU.WHXB19920621

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Brusselator的化学亲合势及熵产生的振荡

高执棣; 李明成; 刘君利   

  1. 北京大学化学系,北京 100871
  • 收稿日期:1991-07-23 修回日期:1992-07-17 发布日期:1992-12-15
  • 通讯作者: 高执棣

The Oscillation of Chemical Affinity and Entropy Production of the Brusselator

Gao Zhi-Di; Li Ming-Cheng; Liu Jun-Li   

  1. Department of Chemistry, Peking University, Beijing 100871
  • Received:1991-07-23 Revised:1992-07-17 Published:1992-12-15
  • Contact: Gao Zhi-Di

关键词: 振荡, 化学亲合势, 熵产生

Abstract: The time variation of chemical affinities A_p and entropy production ? of an open Brusselator system has been studied. It was found that the oscillating characteristics of A_p and ? are quite different. While A_p oscillations with a single peak in every period, ? has either a single peak or two-peak oscillations which depend on the kinetic mechanism of oscillation or values of A_p~?. The meaning to study oscillation of thermodynamic quantities was also discussed.

Key words: Oscillation, Chemical affinity, Entropy production