物理化学学报 >> 1994, Vol. 10 >> Issue (04): 293-296.doi: 10.3866/PKU.WHXB19940402

通讯 上一篇    下一篇

He*(23S)/CO2与CS2反应的化学发光

胡义华, 储焰南, 倪晋智, 李迎春, 李书涛, 曹德兆, 郭敬忠, 刘传朴, 顾月姝   

  1. 中国科学院安徽光学精密机械研究所激光光谱学实验室,合肥 230031|山东大学化学系,济南 250100
  • 收稿日期:1994-01-10 修回日期:1994-02-28 发布日期:1994-04-15
  • 通讯作者: 储焰南

Chemiluminescence of the Reaction of He*(23S)/CO2 with CS2

Hu Yi-Hua, Chu Yan-Nan, Ni Jin-Zhi, Li Ying-Chun, LI  Shu-Chao, Cao De-Zhao, Guo Jing-Zhong, Liu Chuan-Pu, Gu Yue-Shu   

  1. Laser Spectroscopy Laboratory, Anhui Institute of Optics and Fine Mechanics, Academia Sinica, Hefei 230031| Department of Chemistry, Shandong Univeristy, Jinan 250100
  • Received:1994-01-10 Revised:1994-02-28 Published:1994-04-15
  • Contact: Chu Yan-Nan

关键词: 能量转移, 化学发光, CS2, 电荷转移反应

Abstract:

The reaction of He~*(2~3S)/CO_2 with CS_2 has been studied in discharge fiowing-afterglow apparatus. The emission spectra from exited state products CS~+_2(A)、CS (A,a) have been observed. The formation mechbosm proposed is:
CO~+_2(X)+CS_2→CS~+_2(A)+CO_2
CO(a)+CS_2→OCS(X)+CS(A)
CO(a)+CS_2→OCS(X)+CS(a)

Key words: Energy transfer, Chemiluminescence, CS2, Charge-transfer reaction