物理化学学报 >> 1994, Vol. 10 >> Issue (07): 581-584.doi: 10.3866/PKU.WHXB19940702

通讯 上一篇    下一篇

硫转移催化剂研究(I): 组成、结构与吸硫活性关系

王金安, 李承烈, 戴逸云, 高修平   

  1. 华东理工大学石油加工研究所,上海 200237
  • 收稿日期:1994-03-31 修回日期:1994-05-20 发布日期:1994-07-15
  • 通讯作者: 王金安

Investigated on Sulfur-transfer Catalyst(I) Composition,Structure and De-SOx Activity of Magnesium-alumina Spinel

Wang Jin-An, Li Cheng-Lie, Dai Yi-Yun, Gao Xiu-Ping   

  1. Petroleum Processing Research Center, East China University of Science and Technology, Shanghai 200237
  • Received:1994-03-31 Revised:1994-05-20 Published:1994-07-15
  • Contact: Wang Jin-An

关键词: 硫转移催化剂, 铝镁尖晶石, 氧化铈, 催化裂化

Abstract:

Mixed solld solutions magnesium-alumina spinel catalyst, MgAl_2O_4·xAl_2O_3·yMgO (01, the activity decreases which was due to MgO and spinel coexist in the catalyst. The results of reduction-oxidation (red-ox) cycle tests showed that introducing rare earth cerium to spinel could improve the de-SO_x activity. Of all the catalysts, 0.1 Ce/MgAl_2O_4·MgO is promising catalyst which has the highest activity. 30% propane as reducing gas is superior to 30% H_2.

Key words: Sulfur-transfer catalyst, Magnesium-alumina spinel, FCC