物理化学学报 >> 1994, Vol. 10 >> Issue (11): 1055-1058.doi: 10.3866/PKU.WHXB19941118

研究简报 上一篇    

Ni-WC复合电极在弱酸性介质中的析氢催化性能

朱龙章, 刘淑兰, 覃奇贤, 郭鹤桐   

  1. 上海技术师范学院，上海 201418|天津大学应用化学系，天津 300072
  • 收稿日期:1993-09-04 修回日期:1993-12-25 发布日期:1994-11-15
  • 通讯作者: 覃奇贤

Study on the Catalytic Property of Ni-WC Composite Electrode for Hydrogen Evolution Reaction in Weak Acidic Medium

Zhu Long-Zhang, Liu Shu-Lan, Tan Qi-Xian, Guo He-Tong   

  1. Department of Chemical Engineering,Shanghai Teacher's College of Technology,Shanghai 201418|Department of Applied Chemistry,Tianjin University,Tianjin 300072
  • Received:1993-09-04 Revised:1993-12-25 Published:1994-11-15
  • Contact: Tan Qi-Xian

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关键词: 复合电极, 氢析出反应, 活性阴极, 活化自由焓

Abstract:

Ni-WC composite coating was obtained by using composite electrodeposition technique. The behavior of Ni-WC composite coating used as cathode material for hydro gen evolution reaction (HER) in a medium of 0.1 mol .L-1H2SO4+0.5mol.L-1 Na2SO4 was inverstigated. The experimental results show that the catalytic activity of Ni-WC composite electrode for HER in weak acidic medium is appearently higher than that of the electrode plated with Ni and is increased with the increasing of WC content in the coating. As compared with Ni plated electrode, the increase in catalytic activity of the composite electrode for HER should be attributed to the dispersion of WC particles in the Ni deposit, since the mechanism of HER for the two kinds of electrodes is the same. Owing to the incorporation of WC particles in Ni deposit, the standard activation free enthalpy for HER is decreased, and the defects and dislocations in the crystal sturcture of the composite coating are increased. This is equivalent to the addition of catalysis accelerator WC in the catalyst Ni.

Key words: Composite electrode, Hydrogen evolution reaction, Active cathode, Activation free enthalpy