物理化学学报 >> 1995, Vol. 11 >> Issue (03): 202-205.doi: 10.3866/PKU.WHXB19950304

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β-萘甲酰化β-环糊精的分子识别性能研究

郝爱友, 童林荟, 高兴明, 张复升   

  1. 中国科学院兰州化学物理研究所|兰州 730000
  • 收稿日期:1994-11-18 修回日期:1994-12-27 发布日期:1995-03-15
  • 通讯作者: 郝爱友

Studies for the Molecular Recognition Abilities of β-Naphthoated β-Cyclodextrin(β-CD) Derivatives

Hao Ai-You, Tong Lin-Hui, Gao Xing-Ming, Zhang Fu-Sheng   

  1. Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000
  • Received:1994-11-18 Revised:1994-12-27 Published:1995-03-15
  • Contact: Hao Ai-You

关键词: β-萘甲酰化β-环糊精, 主-客体化学, 分子识别, 差紫外光谱

Abstract:

The molecular recognition abilities of β-naphthoated β-CD derivatives as the host compounds were studied: 3-o-β-Naphthoyl-β-CD has a largely improved association constant with cyclohexanol than the corresponding 6-position substituted β-CD derivative has. On the other hand, the polarisablity and the sturcture of the gueset molecule are also important factors which affect the association constant. Cyclohexane may form the 1:2 type inclusion compound with the host compound in this report.

Key words: β-Naphthoated β-CD derivatives, Host-Guest chemistry, Molecular recognition, Difference ultraviolet spectrum

关键词: β-萘甲酰化β-环糊精, 主-客体化学, 分子识别, 差紫外光谱

Abstract:

The molecular recognition abilities of β-naphthoated β-CD derivatives as the host compounds were studied: 3-o-β-Naphthoyl-β-CD has a largely improved association constant with cyclohexanol than the corresponding 6-position substituted β-CD derivative has. On the other hand, the polarisablity and the sturcture of the gueset molecule are also important factors which affect the association constant. Cyclohexane may form the 1:2 type inclusion compound with the host compound in this report.

Key words: β-Naphthoated β-CD derivatives, Host-Guest chemistry, Molecular recognition, Difference ultraviolet spectrum