物理化学学报 >> 1995, Vol. 11 >> Issue (04): 356-359.doi: 10.3866/PKU.WHXB19950414

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溶致变色法测定BMC和MMONS的分子二阶极化率

曹阳,祝志东,赵波   

  1. 苏州大学化学系|苏州 215006
  • 收稿日期:1994-01-03 修回日期:1994-04-30 发布日期:1995-04-15
  • 通讯作者: 祝志东

Determination of Second-order Polarizabilities of BMC and MMONS by Solvatochromic Method

Cao Yang,Zhu Zhi-Dong,Zhao Bo   

  1. Department of Chemistry,Suzhou University,Suzhou 215006
  • Received:1994-01-03 Revised:1994-04-30 Published:1995-04-15
  • Contact: Zhu Zhi-Dong

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关键词: 分子二阶极化率, 溶致变色法, 倍频效应

Abstract:

Second-order polarizabilities of BMC and MMONS were determined by solvatochromic method. The second-order polarizabilities of BMC and MMONS were also calculated by quantum chemical semiempirical CNDO/S-CI method and perturbation theory and second-order nonlinear optical data respectively. Calculated values are in good agreement with experimental results. The effect of molecular and crystal structure on second-order polarizabilities has also been discussed.

Key words: Second-order polarizabilities, Solvatochromic method, Double frequency effect