物理化学学报 >> 1995, Vol. 11 >> Issue (08): 751-754.doi: 10.3866/PKU.WHXB19950817

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C60、C70与丙酮离子体系的气相反应及量化研究

刘子阳, 郝国仑, 王化云, 徐文国, 郭兴华, 马戈, 马登亮, 刘淑莹   

  1. 中国科学院长春应用化学研究所|长春 130022
  • 收稿日期:1994-08-29 修回日期:1994-12-12 发布日期:1995-08-15
  • 通讯作者: 刘子阳

Gas-phase Ion-molecular reactions of C60 and C70 with Acetone and Quantum Chemistry Study

Liu Zi-Yang, Hao Guo-Lun, Wang Hua-Yun, Xu Wen-Guo, Guo Xing-Hua, Ma Ge, Ma Deng-Liang, Liu Shu-Ying   

  1. Changchun Institute of Applied Chemistry,The Chinese Academy Sciences,Changchun 130022
  • Received:1994-08-29 Revised:1994-12-12 Published:1995-08-15
  • Contact: Liu Zi-Yang

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关键词: C60, C70, 丙酮, 离子-分子反应

Abstract:

Gas-phase ion-molecular reactions of C60 and C70 with the ion system of acetone have been studied in this paper. The ions of protoned and acetylized C60 and C70 were formed by the reactions of C60 and C70 with some ions which existed in the ion system when mass spectrometer worked on chemical ionization conditions. The reactivity of C70 is greater than that of C60. Results of quantum chemical calculation for the adduct ions showed a σ bond between the acyl carbon atom and C60 may be formed. These results will provide some valuable informations on the condense-phase acetylization of C60.

Key words: C60, C70, Acetone, Ion-molecular reaction