物理化学学报 >> 1995, Vol. 11 >> Issue (08): 766-768.doi: 10.3866/PKU.WHXB19950821

研究简报 上一篇    

量热法研究Cr3+水解聚合作用的热力学性质

张国鼎,于秀芳   

  1. 西北大学化学系|西安 710069|曲阜师范大学化学系|曲阜 273165
  • 收稿日期:1994-08-25 修回日期:1994-12-25 发布日期:1995-08-15
  • 通讯作者: 张国鼎

Study on the Thermodynamical Functions of the Hydrolytic Polymerization of Chromium(III) Ion by Microcalorimetric Method

Zhang Guo-Xiu,Yu xiu-Fang   

  1. Department of Chemistry,Northwest University,Xi'an 710069|Department of Chemistry,Qufu Normal University,Qufu 273165
  • Received:1994-08-25 Revised:1994-12-25 Published:1995-08-15
  • Contact: Zhang Guo-Xiu

关键词: 微量热法, 热谱, Cr3+离子, 水解平衡常数, 热力学函数

Abstract:

The hydrolytic polymerization of Cr3+ at relative high concentrations have measured by microcalorimetric method. The thermogram have determined using the 2277 Thermoal Activity Monitor. The heat of reaction (△rHm■), the hydrolysis equilibrium constans (K■) and thermodynamical function (△rGm■、△rSm■) at different temperatures have been calculated.

Key words: Microcalorimetry, Thermogram, Chromium(III) ion, Hydrolysis equilibrium constant, Thermodynamical function