物理化学学报 >> 1995, Vol. 11 >> Issue (09): 860-864.doi: 10.3866/PKU.WHXB19950920

研究简报 上一篇    

SiO2/α-FeOOH和SiO2/γ-Fe2O3微粒的界面研究

朱以华,李春忠,胡黎明   

  1. 华东理工大学技术化学物理研究所，上海 200237
  • 收稿日期:1994-09-13 修回日期:1995-04-10 发布日期:1995-09-15
  • 通讯作者: 朱以华

Study on the Interface of SiO2/α-FeOOH and SiO2/γ-Fe2O3 Fine Particles

Zhu Yi-Hua,Li Chun-Zhong,Hu Li-Ming   

  1. East China University of Science and Technology,Institute of Technical Chemical Physics,Shanghai 200237
  • Received:1994-09-13 Revised:1995-04-10 Published:1995-09-15
  • Contact: Zhu Yi-Hua

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关键词: 包敷, 微粒, 界面, 氧化铁

Abstract:

The structures and chemical states of SiO2/α-FeOOH and SiO2/α-Fe2O3 fine particles have been investigated by the technologies of HREM, XPS and CELS. The results show that a crystalline interface layer between SiO2 coating and α-FeOOH nucleus is formed, and its chemical composition is infered to be α-Fe2O3. In view of this, a mechanism of its formation is presented. The results also show that the coating of SiO2/α-Fe2O3 obtained from SiO2/α-FeOOH by a thermal treatment is converted from an amorphous to crystal, line one and its mechanism is discussed. In addition, the effects of the coating on the structure of vacant state above Fermi level of α-FeOOH fine particles have also been studied.

Key words: Coating, Fine particle, Interface, Iron oxide