物理化学学报 >> 1997, Vol. 13 >> Issue (03): 204-206.doi: 10.3866/PKU.WHXB19970304

通讯 上一篇    下一篇

骨架掺硼富勒烯的合成及表征

曹保鹏,周锡煌,施祖进,金朝霞,顾镇南,肖宏展,王敬尊   

  1. 北京大学化学系,北京 100871|北京微量化学研究所,北京 100091
  • 收稿日期:1996-11-27 修回日期:1996-12-28 发布日期:1997-03-15
  • 通讯作者: 顾镇南

Synthesis and Characterization of Boron-Doped Fullerenes

Cao Bao-Peng,Zhou Xi-Huang,Shi Zu-Jin,Jin Zhao-Xia,Gu Zhen-Nan,Xiao Hong-Zhan,Wang Jing-Zun   

  1. Department of Chemistry,Peking University,Beijing 100871|Beijing Institute of Microchemistry,Beijing 100091
  • Received:1996-11-27 Revised:1996-12-28 Published:1997-03-15
  • Contact: Gu Zhen-Nan

关键词: 骨架掺硼富勒烯, 富勒烯, 硼, 碳化硼, 直流电弧法

Abstract:

 Using highly pure graphite rod and B4C/graphite composite rod as electrods, some macroscopic amounts of boron-doped fullerenes, such as C60-nBn and C70-nBn (n=1,2,3) are synthesized by DC arc burning method and extracted by o-xylene from the soots under nitrogen for the first time. The boron-doped fullerenes are characterized by FDMS.

 

Key words: Boron-doped fullerenes, Fullerenes;Boron, Tetra-boron carbide, DC ArC burning method