物理化学学报 >> 1997, Vol. 13 >> Issue (08): 685-692.doi: 10.3866/PKU.WHXB19970803

研究论文 上一篇    下一篇

[IrBr6]2-的反对称极化率与圆偏振激光诱导的ESR谱频移

李莉,何天敬,王秀燕,刘凡镇   

  1. 中国科技大学化学物理系和结构分析中心,合肥 230026
  • 收稿日期:1996-12-09 修回日期:1997-03-14 发布日期:1997-08-15
  • 通讯作者: 刘凡镇

ESR Shift Induced by a Circularly Polarized Laser Beam and Antisymmetric Polarizability of [IrBr6]2-

Li Li,He Tian-Jing,Wang Xiu-Yan,Liu Fan-Zhen   

  1. Department of Chemical Physics and Structure Research Laboratory,University of Science and Technology of China,Hefei 230026
  • Received:1996-12-09 Revised:1997-03-14 Published:1997-08-15
  • Contact: Liu Fan-Zhen

摘要:

在理论上研究了顺磁性粒子体系的圆偏振激光诱导的ESR谱频移效应.给出磁场中分子反对称极化率的公式,并以[IrBr6]2-离子为例讨论了吸收带半高宽的影响.计算了[IrBr6]2-的ESR谱在圆偏振激光作用下的频移.结果发现:在光学共振区附近,ESR频移可达1MHZ的量级,与钠原子体系结果类似.

关键词: 反对称极化率, 激光诱导的ESR谱频移, 过度金属络离子[IrBr6]2-

Abstract:

This paper studies theoretically the effect of circularly polarized laser on ESR spectra in a spin specie system. The antisymmetric polarizability and the laser-induced ESR shift (Δv -- Δv+) of the complex [IrBr6]2- were calculated. The influence of the width г of the absorption line on the ESR shift was discussed. The results show that the ESR shift can be as large as 1MHz order of magnitude at a frequency near optical absorption, which is similar to that of the sodium atom.

Key words: Antisymmetric polarizability, Laser-induced ESR shift, Transition metal complex [IrBr6]2-