物理化学学报 >> 1998, Vol. 14 >> Issue (03): 283-287.doi: 10.3866/PKU.WHXB19980319

研究简报 上一篇    

一种含桥基的三钴羟基硫簇合物的合成与结构

刘启旺, 成庆民, 刘树堂, 胡襄, 黄小荥   

  1. 中国科学院福建物质结构研究所，结构化学国家重点实验室，内蒙古工业大学电力学院，呼和浩特 010080|内蒙古大学化学系，呼和浩特 010021|中国科学院福建物质结构研究所，福州 350002
  • 收稿日期:1900-01-01 修回日期:1997-11-20 发布日期:1998-03-15
  • 通讯作者: 刘启旺

Sytheses and Structures of Co3S(CO)7-clusters Containing a Bridging Bidentate Ligand

Liu Qi-Wang, Cheng Qing-Min, Liu Shu-Tang, Hu Xiang, Huang Xiao-Ying   

  1. State Key Laboratory of Structural Chemistry|Fujian Institute of Research on the Structure of Matter,Academia Sinica|Electric Power College,Inner Mongolia Polytechnic University|The Chemistry Department of Inner Mongolia University|Fujian Institute of Research on the Structure of Matter,Academia Sinica
  • Received:1900-01-01 Revised:1997-11-20 Published:1998-03-15
  • Contact: Liu Qi-Wang

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关键词: 硫代乙内酰脲, 钴羟基簇合物, 合成与结构

Abstract:

 By the reaction of Co2(CO)8 with 2-thiohydantoins S-CNHC(O)C(R1) (R2)NC(O)R3(HL), a new cluster with formula Co3(CO)7 (μ3-S) (μ3, η2-S CNC(O)C(CH3)2N C(O)CH3 has been prepared.
The cluster has been characterized by elemental analysis, IR, 1H NMR and MS spectroscopy. The crystal structure of the cluster has been determined by X-ray single crystal diffraction method. The crystal of the cluster is triclinic, belonging to space group P1 and the cell parameters are as follows: a=8.456 (3), b=11.534(3), c= l1.990(4)A, α=107.36(3), β=108.44(5), γ=90.,18(3)°. The structural analysis shows that this molecule contains a tetrahedral cluster framework Co3S and2-thiohydantoin as bridging ligands links up with two cobalt atoms of the framework by S- and N-atom thus -a five member ring of Co2 NCS has been formed.

Key words: Thiohydantoin, Tricobalt carbonyl cluster, Syntheses and structure