物理化学学报 >> 1998, Vol. 14 >> Issue (09): 811-816.doi: 10.3866/PKU.WHXB19980909

研究论文 上一篇    下一篇

稀土配合物的发光特性及其能量传递研究

于安池, 应立明, 赵新生, 夏立胜, 李琴, 黄春辉   

  1. 北京大学化学与分子工程学院,北京100871|北京大学稀土材料化学及应用国家重点实验室,北京 100871
  • 收稿日期:1997-12-29 修回日期:1998-03-26 发布日期:1998-09-15
  • 通讯作者: 赵新生

Luminescence Properties and Energy Transfer of Rare Earth(III) Complexes

Yu An-Chi, Ying Li-Ming, Zhao Xin-Sheng, Xia Li-Sheng, Li Qin, Huang Chun-Hui   

  1. College of Chemistry and Molecular Enginering,Peking University,Beijing 100871|State Key Laboratory of Rare Earth Materials Chemistry and Applications,Peing University,Beijing 100871
  • Received:1997-12-29 Revised:1998-03-26 Published:1998-09-15
  • Contact: Zhao Xin-Sheng

摘要:

利用激光诱导荧光技术研究了稀土铕等金属配合物的发光特性及其能量传递动力学过程.得到了这些稀土配合物中中心离子Eu(3+)的激发光谱,配体的三线态发时光谱和单线态发射光谱. 在实验上观察到由于中心离子Eu(3+)的5D2←7F0跃迁吸收造成的配体发射光谱中的凹陷行为.

关键词: 稀土配合物, 激光诱导荧光, 能量传递

Abstract:

 The luminescence properties and energy transfer of some rare earth complexes were extensively studied by laser induced fluorescence technique at room temperature. The excitation spectra of central ion (Eu3+ ) was obtained. The excitation spectra from the triplet state and the singlet state of ligand (DBM ) were obtained. It was found that there exists a dip peak in the emission spectra of Eu(DBM )3.2H2O complex because the transition 5D3 -7F0 of the central ionEu3+ absorbs the emission of the ligand DBM (dibenzoylmethane).

Key words: Rare-earth(III) complex, Laser induced fluorescence, Energy transfer