物理化学学报 >> 1999, Vol. 15 >> Issue (05): 458-461.doi: 10.3866/PKU.WHXB19990514

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OTS自组装单分子膜形成过程的AFM研究

徐国华, Higashitani Ko   

  1. 浙江大学化工系，杭州 310027;京都大学化工系，京都 606-01，日本
  • 收稿日期:1998-07-20 修回日期:1998-09-21 发布日期:1999-05-15
  • 通讯作者: 徐国华

Changes of the Surface Adhesion Forces during the Formation of OTS Self-Assembled Monolayer Investigated by AFM

Xu Guo-Hua, Higashitani Ko   

  1. Department of Chemical Engineering,Zhejiang University,Hangzhou 310027;Department of Chemical Engineering,Kyoto University,Kyoto606-01,Japan
  • Received:1998-07-20 Revised:1998-09-21 Published:1999-05-15
  • Contact: Xu Guo-Hu

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关键词: 表面粘滞力, 原子力显微镜(AFM), 十八烷基三氯硅烷(OTS), 自组装单分子膜

Abstract:

Changes of the surface adhesion forces during the formation of octadecyltrichlorosilane (OTS) self assembled monolayer on glass substrate surface was investigated by Atomic Force Microscope (AFM). The research showed that as the reaction proceeded, the hydrophobicities and the adhesion forces of the sample surfaces increased gradually. After 15 min reaction, the glass surface was completely hydrophobic with an advancing contact angle of 105° and an interfacial energy of 55. 79 mJ•m-2.

Key words: Surface adhesion force, Atomic Force Microscope(AFM), Octadecyltrichlorosilane(OTS), Self-assembled monolayer