物理化学学报 >> 1999, Vol. 15 >> Issue (07): 643-646.doi: 10.3866/PKU.WHXB19990712

研究简报 上一篇    下一篇

CH2(X 3B1)与NO的基元化学反应研究

杨继新, 苏红梅, 毛文涛, 钟晋贤, 孔繁敖   

  1. 中国科学院化学研究所 分子反应动力学国家重点实验室，北京 100080|中国科学院生态环境研究中心，北京 100085
  • 收稿日期:1998-07-03 修回日期:1998-10-29 发布日期:1999-07-15
  • 通讯作者: 孔繁敖

TR-FTIR Study of the Reaction CH2(X3B1)+NO

Yang Ji-Xin, Su Hong-Mei, Mao Wen-Tao, Zhong Jin-Xian, Kong Fan-Ao   

  1. The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080|Reaearch Center for Eco-Environmental Sciences Chinese Academy of Sciences,Beijing 100085
  • Received:1998-07-03 Revised:1998-10-29 Published:1999-07-15
  • Contact: Kong Fan-Ao

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关键词: CH2(X3B1), 态-态反应, TR-FTIR;NO

Abstract:

The reaction of methylene radicals in their 3 B1 electronic ground state with molecular NO was studied. Pure CH2(X 3 B1 ) radicals were produced by UV photolysis of ketene at 351 nm. The products were measured by Time-Resolved Fourier Transform Infrared (TR-FTIR) spectrometer. CO.OH .NH2 and HOCN or its isomer HNCO were found as primary products and several possible channels of this reaction were suggested.

Key words: CH2(X3B1), State-specific reaction, TR-FTIR;NO