物理化学学报 >> 2000, Vol. 16 >> Issue (01): 65-69.doi: 10.3866/PKU.WHXB20000113

研究简报 上一篇    下一篇

硅胶键合杯[4]芳烃固定相的合成和核磁共振表征

张岩, 肖湘竹, 冯钰锜, 达世禄, 裘鉴卿, 叶朝辉   

  1. 中国科学院武汉物理与数学研究所，波谱与原子分子物理国家重点实验室，武汉 430071|武汉大学化学系，武汉 430072
  • 收稿日期:1999-02-11 修回日期:1999-05-06 发布日期:2000-01-15
  • 通讯作者: 裘鉴卿

Preparation and Nuclear Magnetic Resonance Characterizations of a Silica-bonded Calix[4]arene Stationary Phase

Zhang Yan, Xiao Xiang-Zhu, Feng Yu-Qi, Da Shi-Lu, Qiu Jian-Qing, Ye Chao-Hui   

  1. Laboratory of Magnetic Resonance and Atomic and Molecular Physics,Wuhan Institute of Physics and Mathematics,The Chinese Academy of Sciences,Wuhan 430071|Chemistry Department of Wuhan University,Wuhan 430072
  • Received:1999-02-11 Revised:1999-05-06 Published:2000-01-15
  • Contact: Qiu Jian-Qing

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关键词: 键合杯芳烃, 固定相, 交叉极化和魔角旋转(CP/MAS), 固体核磁共振

Abstract:

A new method was used to prepare a calix [4] arene-bonded silica stationary phase. The chemically modified calix[4] arene 1 was attached to silica gel via the silane coupling reagent γ-(ethylenediamino ) -propyl-triethoxyl-silane. The resulting bonded phase was characterized by 29 Si and 13C cross polarization/magic angle spinning(CP/MAS) nuclear magnetic resonance(NMR) techniques.

Key words: Silica-bonded calixarenes, Stationary phase, CP/MAS, NMR