物理化学学报 >> 2000, Vol. 16 >> Issue (09): 769-771.doi: 10.3866/PKU.WHXB20000901

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以癸二胺为模板合成十聚钨酸多孔材料

邵柯, 马颖, 陈朝晖, 姚建年   

  1. 中国科学院化学研究所分子科学中心，北京 10080
  • 收稿日期:2000-05-22 修回日期:2000-06-15 发布日期:2000-09-15
  • 通讯作者: 姚建年 E-mail:jnyao@ipc.ac.cn

Synthesis of Decatungstate Microporous Materials Using 1,10-diaminodecane as Template

Shao Ke, Ma Ying, Chen Chao-Hui, Yao Jian-Nian   

  1. Centre for Malecular Sclence,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
  • Received:2000-05-22 Revised:2000-06-15 Published:2000-09-15
  • Contact: Yao Jian-Nian E-mail:jnyao@ipc.ac.cn

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关键词: 十聚钨酸, 多孔材料, 癸二胺, 模板合成

Abstract:

A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical conditions. This material was constructed from highly ordered hexagonal array of 1,10-diaminodecane and decatungstate polyanions. HR-TEM image showed that the decatungstate polyanions "packed" around the l,10-diaminodecane molecules. XRD pattern confirmed its hexagonal array(a=b=1.718nm,cunaknown). A template mechanism was pro-posed to explain its formation process. It is evidenced that l,10-diaminodecane molecules play a crucial role in templating the inorganic framework. the cationic diaminodecane molecules "bond" decatungstate polyanions on each end via supermolecular interaction and thus form bolarform structure units. These units pack together and a hexagonal phase is constructed.

Key words: Decatungstate, microporous materials, 1,10-diaminodecane, templating synthesis