物理化学学报 >> 2000, Vol. 16 >> Issue (12): 1115-1118.doi: 10.3866/PKU.WHXB20001210

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氯化镧与甘氨酸配位反应的热化学研究

周传佩, 陈文生, 刘义, 李林尉, 屈松生   

  1. 武汉大学化学与环境科学学院 武汉 430072|湖北药检高等专科学校 武汉 430064|湖北教育学院 武汉 430060
  • 收稿日期:2000-04-18 修回日期:2000-07-10 发布日期:2000-12-15
  • 通讯作者: 刘义 E-mail:Liu Yi@Public.wh.hb.cn

Thermovhemical Study of the Reaction of Lanthanum Chloride Coordinated with Glycine

Zhou Chuan-Pei, Chen Wen-Sheng, Liu Yi, Li Lin-Wei, Qu Song-Sheng   

  1. College of Chemistry and Environment Science,Wuhan 430072|Hubei College of Pharmacy and Clinical LabortoryScience,Wuhan 430064|Hubei Education College,Wuhan 430060
  • Received:2000-04-18 Revised:2000-07-10 Published:2000-12-15
  • Contact: Liu Yi E-mail:Liu Yi@Public.wh.hb.cn

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关键词: 热化学, 氯化镧, 甘氨酸, 标准生成焓

Abstract:

The reaction enthalpy of coordination reaction of lanthanum chloride with Glycine is determined by solution calorimetry in an isoperibel reaction calorimeter.The calormetric solvent is the solution of hydrochloric acid (2 mol L-1),a new thermochemical cycle is designed.According to the results,the following date: ΔrHΘm(298.2K)=-4.310kJ mol-1 ΔrHΘm(La(Gly)3Cl3 5H2O,s,298.2K)=-4222.93kJ mol-1 were obtained.

Key words: Thermochemistry, Lanthanum cholride, Glycine, Standard enthalpy of formation