物理化学学报 >> 2001, Vol. 17 >> Issue (01): 87-90.doi: 10.3866/PKU.WHXB20010119
Wang Guo-Ping;Zhu Long-Guan
Abstract: EPR spectra of three new quaternary gadolinium complexes(I：[Gd(C6H5COO)2(NO3)(bipy)]2,Ⅱ：[Gd(mCH3C6H4COO)2(NO3)(phen)]2 and Ⅲ：[Gd(pCH3C6H4COO)(NO3)(phen)]2) with mixed anion ligands in polycrystalline powders and solutions have been investigated at different temperatures and solvents.New behavior of EPR spectra of complex Ⅲ was first observed in polycrystalline powder at 77K and three types of EPR spectra for three complexes,symmetry resonance spectrum for the complex Ⅱ,U spectrum for the complex Ⅲ,and asymmetry resonance spectrum for the complex I.The relationship of EPR features between the crystalfield strength in the complexes and local symmetry around Gd(Ⅲ) was discussed.The crystalfield parameters b20 and asymmetry parameters λ′ of the complexes I and Ⅲ were estimated.
Quaternary mixed anion complex,
王国平;朱龙观. 钆(Ⅲ)混合阴离子配合物的电子顺磁共振谱[J]. 物理化学学报, 2001, 17(01): 87-90.
Wang Guo-Ping;Zhu Long-Guan. EPR Properties of Novel Quaternary Mixed Anion Complexes of Gadolinium(Ⅲ)[J]. Acta Phys. -Chim. Sin., 2001, 17(01): 87-90.
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