物理化学学报 >> 2002, Vol. 18 >> Issue (05): 451-454.doi: 10.3866/PKU.WHXB20020514

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仿贝壳自组装纳米复合薄膜的制备及结构表征

张晟卯;高永建;张治军;党鸿辛;刘维民;薛群基   

  1. 河南大学特种功能材料重点实验室,开封　475001; 中国科学院兰州化学物理研究所固体润滑开放实验室,兰州　730000
  • 收稿日期:2001-10-30 修回日期:2001-12-13 发布日期:2002-05-15
  • 通讯作者: 张治军 E-mail:zhangshengmao@263.net

Preparation and Characterization of Selfassembly Nanocomposite Thin Film

Zhang Sheng-Mao;Gao Yong-Jian;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji   

  1. Lubrication and Functional Material laboratory, Henan University,Kaifeng　475001; 1State key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou　730000
  • Received:2001-10-30 Revised:2001-12-13 Published:2002-05-15
  • Contact: Zhang Zhi-Jun E-mail:zhangshengmao@263.net

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摘要： 利用超分子自组装方法在普通玻璃表面制备了仿贝壳有机无机复合纳米薄膜.采用X射线衍射仪、傅立叶红外光谱仪、紫外可见吸收光谱仪、透射电子显微镜对薄膜结构进行了表征.结果表明这种薄膜具有有机无机有序交替的层状纳米复合结构，聚合前层间距为4.20 nm，聚合后层间距为3.91 nm.无机层由TiO2纳米微粒构成.

关键词: 超分子自组装, 有机-无机杂化, 纳米复合, 仿贝壳, 薄膜

Abstract: The TiO2/organic composite thin film was prepared using supermolecular selfassembly method on glass substrate. The structure of the thin film was characterized by FTIR, UVVis, XRD and TEM techniques. The results indicated that the thin film was composed of alternative orderly appeared organic and inorganic layers. The distance between organic layer and inorganic layer was 4.20 nm before polymerization and 3.91 nm after polymerization, respectively. The inorganic layers were composed of TiO2 nanoparticles.

Key words: Supermolecular selfassembly, Organicinorganic hybird, 　Nanocomposition, Mimicking nacre, Thin film