物理化学学报 >> 2004, Vol. 20 >> Issue (08S): 982-988.doi: 10.3866/PKU.WHXB200408zk14

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自组装单分子膜包覆的金属纳米粒子的电化学研究

李迪;李景虹   

  1. 中国科学院长春应用化学研究所电分析化学国家重点实验室，长春　130022
  • 收稿日期:2003-12-18 修回日期:2004-03-09 发布日期:2004-08-15
  • 通讯作者: 李景虹 E-mail:lijingh@ciac.jl.cn

Electrochemistry of Monolayer Protected Nanoclusters

Li Di;Li Jing-Hong   

  1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun　130022
  • Received:2003-12-18 Revised:2004-03-09 Published:2004-08-15
  • Contact: Li Jing-Hong E-mail:lijingh@ciac.jl.cn

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摘要： 介绍了近年来自组装单分子膜包覆的金属纳米粒子这一领域的最新发展，包括单分子层膜包裹的纳米粒子的合成、衍生化、光学和电化学性质及应用，其中重点介绍了其量子化充电现象.对该领域的深入研究将大大地促进化学、生物科学、材料科学和纳米电子学等前沿学科的发展.

关键词: 自组装膜, 纳米材料, 电化学, 量子化充电行为

Abstract: In this review, we evaluate the present state in the field of monolayer protected metal nanoclusters with regard to their synthesis, their optical and electrochemical properties and applications. Their quantum capacitance charging phenomenon and electroactive monolayer protected nanoclusters were especially stressed. Finally, we canvass some of the important remaining research opportunities in this field and present a brief outlook. We believe that progresses in this field would greatly promote the development of chemistry, biochemistry and material chemistry.

Key words: Monolayer protected nanoclusters, Nanomaterial, Electrochemistry, 　Quantum capacitance charging