物理化学学报 >> 2004, Vol. 20 >> Issue (11): 1287-1291.doi: 10.3866/PKU.WHXB20041101

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化学修饰阳极氧化铝模板法合成小尺寸聚苯胺纳米线

周剑章; 董平; 蔡成东; 林仲华   

  1. 厦门大学固体表面物理化学国家重点实验室，化学系，物理化学研究所，厦门　361005
  • 收稿日期:2004-07-27 修回日期:2004-08-28 发布日期:2004-11-15
  • 通讯作者: 林仲华 E-mail:zhlin@xmu.edu.cn

Chemically Modified AAO Template and Application to PANI Nanowires Synthesis

Zhou Jian-Zhang; Dong Ping; Cai Cheng-Dong; Lin Zhong-Hua   

  1. State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, Institute of Physical Chemistry, Xiamen University, Xiamen　361005
  • Received:2004-07-27 Revised:2004-08-28 Published:2004-11-15
  • Contact: Lin Zhong-Hua E-mail:zhlin@xmu.edu.cn

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摘要： 利用表面活性剂对阳极氧化铝(AAO)模板进行化学修饰，发展了模板合成法，从而得到更小尺寸的聚苯胺纳米管、线.在表面活性剂十八烷基脂肪酸(R18)修饰下，在14 nm孔径的AAO模板中合成7 nm的纳米线.对不同表面活性剂的比较后发现,通过改变修饰表面活性剂上烷基链长可以对所制备的聚合物纳米管、线的直径进行调控.

关键词: 模板的化学修饰, 　AAO模板, 　小尺寸聚合物纳米线

Abstract: A novel strategy has been developed to fabricate PANI nanowires or nanotubes with smaller diameter in AAO template by chemical modification of selected surfactants. With the assistance of surfactant octadecanoic acid (R18), we got the PANI nanowires which diameter is 7 nm in AAO pores with a diameter of 14 nm. By comparing different surfactants, we concluded that by assembling selected surfactant with different length alky group to AAO templates, the diameters of polymer nanowires or nanotubes could be controlled.

Key words: Chemical modification of template, 　AAO template, 　Small-scale polymer nanowires