物理化学学报 >> 2005, Vol. 21 >> Issue (09): 1050-1054.doi: 10.3866/PKU.WHXB20050921

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玻璃基片上纳米碳管电极的集成

王升高; 赵修建; 韩建军; 汪建华   

  1. 武汉理工大学硅酸盐材料工程教育部重点实验室, 武汉 430070; 武汉工程大学等离子体化学与新材料重点实验室, 武汉 430073
  • 收稿日期:2005-01-19 修回日期:2005-03-24 发布日期:2005-09-15
  • 通讯作者: 王升高 E-mail:wyysg@163.com

Integration of Carbon Nanotubes Electrodes on Glass Substrate

WANG Sheng-gao; ZHAO Xiu-jian; HAN Jian-jun; WANG Jian-hua   

  1. Key Laboratory for Silicate Materials Science and Engineering of Ministry of Education, Wuhan University of Technology, Wuhan 430070; Provincial Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan 430073
  • Received:2005-01-19 Revised:2005-03-24 Published:2005-09-15
  • Contact: WANG Sheng-gao E-mail:wyysg@163.com

摘要: 利用微波等离子体化学气相沉积法在玻璃孔穴中定位生长纳米碳管电极, 分析了负偏压对纳米碳管电极生长的影响. 该电极对铜离子的电化学检测性能分析结果表明, 所制备的纳米碳管电极具有良好的电化学检测性能, 位于-0.0100 V附近的铜离子的还原峰峰形良好, 其电流在铜离子浓度为0.01~0.30 mmol•L-1时, 与Cu2+浓度呈良好的线性关系, 相关系数为0.9975, 且具有较好的长期稳定性和重现性.

关键词: 纳米碳管电极, 电化学检测, 微波等离子体化学气相沉积法

Abstract: Carbon nanotubes electrodes were prepared in the holes of glass directly by microwave plasma chemical vapor deposition. During the process of carbon nanotubes growth, the negative bias imposed on the substrate could improve the alignment of carbon nanotubes. The electrochemical behavior of CuSO4 at the carbon nanotubes electrode was investigated. Compared to graphite electrode, carbon nanotubes had excellent electrochemical behavior for the analysis of Cu2+. The current had linearship with the Cu2+ concentration in the range of 0.01~0.30 mmol•L-1, and the correlation coefficient was 0.9975. Because carbon nanotubes were integrated directly on the substrate, the stable response to Cu2+ solution showed that the carbon nanotubes electrodes had long-term stability.

Key words: Carbon nanotubes electrode, Electrochemical detection, Microwave plasma chemical vapor deposition