Please wait a minute...
物理化学学报  2006, Vol. 22 Issue (05): 528-531    DOI: 10.3866/PKU.WHXB20060503
研究论文     
三维有序多孔图案化SiC陶瓷的制备
王浩;李效东;金东杓
国防科学技术大学新型陶瓷纤维及其复合材料重点实验室, 长沙410073；忠南大学精细化工与化学工程系, 大田305-764, 韩国
Preparation of Three-dimensionally Ordered Macroporous SiC Patterns
WANG Hao;LI Xiao-Dong;KIM Dong-Pyo
Key Laboratory of Advanced Ceramic Fiber and Its Composites of National University of Defense Technology, Changsha 410073, P. R. China； Department of Fine Chemical Engineering and Chemistry of Chungnam National University, Taejon 305-764, South Korea
 全文: PDF(975 KB)   输出: BibTeX | EndNote (RIS) |
摘要： 结合毛细管微模塑技术、模板技术和先驱体转化技术, 以图案化聚二甲基硅氧烷(PDMS)弹性体为模具,以氧化硅凝胶小球为模板, 以液态聚碳硅烷(PCS)为先驱体, 经过氧化硅凝胶小球图案化模板的形成, 先驱体的渗入, 模板中先驱体的交联, 弹性模具的去除, 图案化先驱体的无机化和模板的去除, 制备了图案化多孔SiC 陶瓷.研究结果表明：所制备的图案化多孔陶瓷中, 图案的尺寸受图案化PDMS 弹性模具的控制, 球形孔的孔径可由氧化硅凝胶小球来调节. 图案化陶瓷中球形孔不仅三维有序排列, 而且由于模板中小球的相互接触形成的“窗 口”使球形孔三维贯通.
关键词： 图案化;  模板技术;  先驱体转化技术;  三维有序大孔材料;  SiC陶瓷    
Abstract: Three-dimensionally ordered macroporous(3DOM) SiC patterns were fabricated successfully on silicon substrate using polydimethylsiloxane (PDMS) elastometric stamp as mold, silica spheres as template, polycarbosilane (PCS) as preceramic polymer. The preparing process included the formation of patterned silica template, precursor infiltration into the template, curing of the precursor, demolding of PDMS mold, pyrolysis of the cured preceramic polymer pattern and etching of the silica template. The results show that the dimension of SiC pattern can be controlled by using PDMS molds with different dimensions and the pore diameter in the patterned porous ceramic can be tailored by using different sizes of silica sphere template. The pores pack together to be a three-dimensionally ordered structure and the small windows originated from the contacting points of the silica spheres endow the porous patterns with a three-dimensionally penetrated structure. The prepared macroporous ceramic patterns will be potentially applied in chemical harsh conditions due to the advanced properties of the SiC ceramic.
Key words: Pattern    Templated technique    Preceramic polymer conversion technique    3DOMmaterial    SiC ceramic
收稿日期: 2005-08-25 出版日期: 2006-04-28
通讯作者: 王浩     E-mail: whlucky2002@hotmail.com
服务　　
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章　　
王浩
李效东
金东杓

引用本文:

王浩;李效东;金东杓. 三维有序多孔图案化SiC陶瓷的制备[J]. 物理化学学报, 2006, 22(05): 528-531, 10.3866/PKU.WHXB20060503

WANG Hao;LI Xiao-Dong;KIM Dong-Pyo. Preparation of Three-dimensionally Ordered Macroporous SiC Patterns. Acta Phys. -Chim. Sin., 2006, 22(05): 528-531, 10.3866/PKU.WHXB20060503.

链接本文:

http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB20060503    或    http://www.whxb.pku.edu.cn/CN/Y2006/V22/I05/528

[1] 李浙齐, 王特华, 李秀媛, 张雅琴, 纪敏. 三维有序大孔MgFe0.1Al1.9O4催化剂制备及其催化乙苯与CO2氧化脱氢的性能[J]. 物理化学学报, 2015, 31(4): 743-749.
[2] 李磊, 钟雅文, 陈财康, 李剑. 基于静态呼吸图技术的图案化方法[J]. 物理化学学报, 2010, 26(04): 1135-1142.
[3] 梁山, 薛群基, 崔玉红, 赵占芬. 水溶液法制备图案化TiO2薄膜[J]. 物理化学学报, 2010, 26(02): 502-506.
[4] 王晓冬;仪桂云;董鹏;陈胜利. 悬浮液气-液界面二元胶体颗粒的漂浮组装机理[J]. 物理化学学报, 2007, 23(11): 1707-1713.
[5] 白硕;杨凌露;张茂峰;杨朝晖;张智峰;曹维孝. 具有超疏水性质的图案化Ag膜[J]. 物理化学学报, 2006, 22(10): 1296-1299.