物理化学学报 >> 2006, Vol. 22 >> Issue (08): 981-986.doi: 10.3866/PKU.WHXB20060815

研究论文 上一篇    下一篇

新型手性基团修饰的金属卟啉的合成及性质研究

王树军;章应辉;阮文娟;罗代兵;朱志昂;田建国;刘智波   

  1. 廊坊师范学院化学与材料科学学院, 河北廊坊;065001;南开大学化学系,天津300071;南开大学泰达应用物理学院,天津300071
  • 收稿日期:2006-01-16 修回日期:2006-04-04 发布日期:2006-08-04
  • 通讯作者: 阮文娟 E-mail:wjruan@nankai.edu.cn

Studies on the Synthesis and Characters of a Novel Chiral Metalloprophyrin

WANG Shu-Jun;ZHANG Ying-Hui;RUAN Wen-Juan;LUO Dai-Bing;ZHU Zhi-Ang;TIAN Jian-Guo;LIU Zhi-Bo   

  1. College of Chemistry and Material Science, Langfang Teachers College, Langfang 065001, P. R. China; Department of Chemistry, Nankai University, Tianjin 300071, P. R. China;3Applied Physics School of Teda, Nankai University, Tianjin 300071, P. R. China
  • Received:2006-01-16 Revised:2006-04-04 Published:2006-08-04
  • Contact: RUAN Wen-Juan E-mail:wjruan@nankai.edu.cn

摘要: 合成了一种手性基团修饰的金属卟啉化合物[5-对(L-亮氨酰氧乙氧基)苯基-10, 15, 20-三苯基卟啉锌]. 通过元素分析、紫外可见光谱、红外光谱、圆二色光谱及核磁共振波谱对该化合物进行了较详细的表征. 同时, 采用分子力学方法搜索了主体的最低能量构象, 从理论上进一步解释实验结果. 利用Z扫描技术测定了该化合物的三阶非线性光学性质.

关键词: 手性金属卟啉, 圆二色光谱, 理论计算, 非线性光学性质

Abstract: One kind of novel chiral Zn porphyrin was synthesized. By means of elementary analysis, UV-Vis, IR, CD spectrum, and 1H-NMR, the chiral Zn porphyrin was charactered. The lowest energy conformation of the chiral zinc porphyrin was obtained by system search on the basis of Tripos force field. Nonlinear optical properties of the chiral porphyrin complexes were studied and refractive indexes were measured by Z-scan techniques. The result indicates that chiral zinc porphyrin has biggish nonlinear refractive index. This is an effective method by modifying chiral structure of porphyrin complexes to increase nonlinear refractive index.

Key words: Chiral metalloporphyrin, CD spectrum, Theoretical calculation, Nonlinear optical properties