物理化学学报 >> 2008, Vol. 24 >> Issue (06): 1090-1094.doi: 10.3866/PKU.WHXB20080631

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酚醛树酯的热解动力学模型

马伟; 王苏; 崔季平; 张胜涛; 范秉诚; 何宇中   

  1. 中国科学院力学研究所高温气体动力学重点实验室, 北京 100190; 重庆大学化学化工学院, 重庆 400044
  • 收稿日期:2007-11-02 修回日期:2008-02-28 发布日期:2008-06-03
  • 通讯作者: 王苏 E-mail:suwang@imech.ac.cn

Thermal Decomposition Kinetic Model of Phenolic Resin

MA Wei; WANG Su; CUI Ji-Ping; ZHANG Sheng-Tao; FAN Bing-Cheng; HE Yu-Zhong   

  1. Key Laboratory of High Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, P. R. China; College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China
  • Received:2007-11-02 Revised:2008-02-28 Published:2008-06-03
  • Contact: WANG Su E-mail:suwang@imech.ac.cn

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摘要： 建立了一种利用热重峰值分析进行酚醛树酯热解动力学研究的方法, 这种方法利用热重谱峰上几个特征点的数据来确定动力学参数. 根据酚醛树酯热解DTG曲线的特点, 把酚醛树酯的热解过程分解成三个阶段, 用峰值分析法对每个反应阶段分别建模, 通过三个反应阶段的叠加得到了一个酚醛树酯分阶段热解动力学模型, 该模型能够很好地描述酚醛树酯的热解过程.

关键词: 酚醛树酯, 热分解, 动力学模型, 热分析, 峰值分析法

Abstract: A method used for the study of thermal decomposition kinetics by peak analysis was developed. This method needs only a few eigenvalues of the thermogravimetric mass loss curves for the determination of kinetic parameters. A peak separation was performed to separate the thermal decomposition of phenolic resin into three stages according to the characteristic of the experimental differential mass loss curve. Kinetic parameters for each stage were determined using peak analysis method. A decomposition kinetic model, which was shown to accurately describe the decomposition process of phenolic resin, was obtained by the combination of these three stages.

Key words: Phenolic resin, Thermal decomposition, Kineticmodel, Thermal analysis, Peak analysismethod

MSC2000: 

  • O643