物理化学学报 >> 2009, Vol. 25 >> Issue (01): 13-18.doi: 10.3866/PKU.WHXB20090103

研究论文 上一篇    下一篇

卤素双原子分子部分电子态的完全振动能谱和离解能

渠双双; 孙卫国; 王宇杰; 樊群超   

  1. 四川大学原子与分子物理研究所, 成都 610065
  • 收稿日期:2008-07-04 修回日期:2008-09-26 发布日期:2008-12-31
  • 通讯作者: 孙卫国 E-mail:weiguosun@x263.net

Full Vibrational Energy Spectra and Dissociation Energies for Some Electronic States of Diatomic Halogen Molecules

QU Shuang-Shuang; SUN Wei-Guo; WANG Yu-Jie; FAN Qun-Chao   

  1. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, P. R. China
  • Received:2008-07-04 Revised:2008-09-26 Published:2008-12-31
  • Contact: SUN Wei-Guo E-mail:weiguosun@x263.net

摘要: 用代数方法(AM)可以获得双原子分子包含最高振动能级在内的所有高阶振动能级的完全振动能谱; 基于Leroy和Bernstein的能级表达式, 研究了卤族元素双原子分子Cl2-A’3∏(2u)、Br2-X1∑+g和I2-0+u电子态的完全振动能谱和离解能, 得到的理论结果与实验符合得很好.

关键词: 代数方法, 振动能级, 离解能, 卤素分子, 双原子分子

Abstract: The algebraic method (AM) and a new formula for dissociation energy were used to study full vibrational energies {EAMυ} and dissociation energies DAMe of three electronic states Cl2-A’3∏(2u), Br2-X1∑+g, and I2-0+uof diatomic halogen molecules. The obtained results are in agreement with known experimental data.

Key words: Algebraic Method, Vibrational energy, Dissociation energy, Halogen molecule, Diatomic molecule

MSC2000: 

  • O641