物理化学学报 >> 2010, Vol. 26 >> Issue (08): 2087-2095.doi: 10.3866/PKU.WHXB20100639

综述 上一篇    下一篇

水溶性大分子调控碳酸钙结晶的研究进展

杨效登, 沈强, 徐桂英   

  1. 山东大学胶体与界面化学教育部重点实验室, 济南 250100
  • 收稿日期:2010-01-26 修回日期:2010-03-13 发布日期:2010-07-23
  • 通讯作者: 徐桂英 E-mail:xuguiying@sdu.edu.cn
  • 基金资助:

    国家自然科学基金(20833010)资助项目

Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules

YANG Xiao-Deng, SHEN Qiang, XU Gui-Ying   

  1. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China
  • Received:2010-01-26 Revised:2010-03-13 Published:2010-07-23
  • Contact: XU Gui-Ying E-mail:xuguiying@sdu.edu.cn
  • Supported by:

    The project was supported by the National Natural Science Foundation of China (20833010).

摘要:

结合本课题组的工作综述了水溶性大分子调控碳酸钙合成的研究进展. 通过分析生物大分子、合成大分子以及大分子/表面活性剂混合体系对碳酸钙结晶习性的影响, 讨论了水溶性大分子对碳酸钙形貌和晶型的调控机理. 大分子调控碳酸钙合成的研究不仅为人们制备不同形貌、尺寸和晶型的碳酸钙开拓了思路, 也为满足不同的工业需求提供了理论指导.

关键词: 水溶性大分子, 碳酸钙, 结晶, 晶型, 形貌

Abstract:

The influence of water-soluble macromolecules on the crystallization of calcium carbonate is reviewed combining with our work. The mechanisms are interpreted based on the analysis of calcium carbonate crystallization in the presence of biomacromolecules, synthetic polymers, or mixtures of the polymer and surfactants. This paper provides not only the methods for the crystallization of calcium carbonate consisting of different resultant morphologies, polymorphs, and sizes, but also a theoretical guide for industrial production.

Key words: Water soluble polymer, Calcium carbonate, Crystallization, Polymorph, Morphology

MSC2000: 

  • O645