物理化学学报 >> 2010, Vol. 26 >> Issue (08): 2171-2176.doi: 10.3866/PKU.WHXB20100646

电化学 上一篇    下一篇

Kopsia Singapurensis 提取物对酸性介质中低碳钢的缓蚀效应

RAJA Pandian Bothi1, RAHIM Afidah Abdul1, OSMAN Hasnah1, AWANG Khalijah1   

  1. School of Chemical Sciences, University Sains Malaysia, 11800 Penang, Malaysia; Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • 收稿日期:2010-01-14 修回日期:2010-03-24 发布日期:2010-07-23
  • 通讯作者: RAHIM Afidah Abdul E-mail:afidah@usm.my

Inhibitory Effect of Kopsia Singapurensis Extract on the Corrosion Behavior ofMild Steel in AcidMedia

RAJA Pandian Bothi1, RAHIM Afidah Abdul1, OSMAN Hasnah1, AWANG Khalijah1   

  1. School of Chemical Sciences, University Sains Malaysia, 11800 Penang, Malaysia; Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • Received:2010-01-14 Revised:2010-03-24 Published:2010-07-23
  • Contact: RAHIM Afidah Abdul E-mail:afidah@usm.my
  • Supported by:

    The project was supported by the USM Research Fund, Malaysia (RU-1001/229/PKIMIA/811006, FRGS-203/PKMIA/671030).

摘要:

The influence of the alkaloid extract of Kopsia singapurensis on the corrosion behavior of mild steel (MS) in 1 mol·L-1 HCl and 1 mol·L-1 H2SO4 was studied using electrochemical techniques, viz., potentiodynamic polarization and AC impedance. The experimental results clearly show that the plant extract effectively inhibits corrosion in both acid media and the inhibition efficiency obtained from the electrochemical techniques is in good agreement. Furthermore, the polarization technique indicates that the extract acts as an anodic type inhibitor in HCl and as a mixed type in H2SO4. Scanning electron microscopy (SEM) was carried out to examine the surface morphological changes of metal specimens in both the inhibited and uninhibited solutions. SEM images show the formation of an adsorbed layer over the metal surface by the inhibitor molecule. The presence of alkaloidal constituents in the plant extract was confirmed by Fourier transform infrared (FTIR) spectroscopy and chemical analysis.

关键词: Corrosion inhibitor, Kopsia singapurensis, Mild steel, Polarization, Impedance, SEM, FTIR

Abstract:

The influence of the alkaloid extract of Kopsia singapurensis on the corrosion behavior of mild steel (MS) in 1 mol·L-1 HCl and 1 mol·L-1 H2SO4 was studied using electrochemical techniques, viz., potentiodynamic polarization and AC impedance. The experimental results clearly show that the plant extract effectively inhibits corrosion in both acid media and the inhibition efficiency obtained from the electrochemical techniques is in good agreement. Furthermore, the polarization technique indicates that the extract acts as an anodic type inhibitor in HCl and as a mixed type in H2SO4. Scanning electron microscopy (SEM) was carried out to examine the surface morphological changes of metal specimens in both the inhibited and uninhibited solutions. SEM images show the formation of an adsorbed layer over the metal surface by the inhibitor molecule. The presence of alkaloidal constituents in the plant extract was confirmed by Fourier transform infrared (FTIR) spectroscopy and chemical analysis.

Key words: Corrosion inhibitor, Kopsia singapurensis, Mild steel, Polarization, Impedance, SEM, FTIR