物理化学学报 >> 2010, Vol. 26 >> Issue (07): 1852-1859.doi: 10.3866/PKU.WHXB20100738

催化和表面结构 上一篇    下一篇

高温水热合成具有高稳定性的有序介孔材料

刘思宇, 孟祥举, 肖丰收   

  1. 浙江大学化学系催化研究所, 浙江省应用化学重点实验室, 杭州 310007
    吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春 130012
  • 收稿日期:2010-01-21 修回日期:2010-04-28 发布日期:2010-07-02
  • 通讯作者: 肖丰收 E-mail:fsxiao@mail.jlu.edu.cn

Hydrothermal Synthesis of Ordered Mesoporous Materials with High Stability at High Temperatures

LIU Si-Yu, MENG Xiang-Ju, XIAO Feng-Shou   

  1. Key Laboratory of Applied Chemistry of Zhejiang Province, Institute of Catalysis, Department of Chemistry, Zhejiang University, Hangzhou 310007, P. R. China
    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
  • Received:2010-01-21 Revised:2010-04-28 Published:2010-07-02
  • Contact: XIAO Feng-Shou E-mail:fsxiao@mail.jlu.edu.cn

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摘要：

高温水热合成路线作为合成具有超高稳定性的介孔材料越来越受到人们的重视. 本文对高温水热合成有序介孔材料的发展过程作一个简单的综述, 合成路线包括使用碳氟表面活性剂和碳氢表面活性剂作为复合模板, 有机季铵盐与碳氢表面活性剂作为复合模板以及最近报道的采用碳氢表面活性剂作为单一模板来合成系列的有序介孔材料, 其组成为二氧化硅、氧化钛硅以及聚合物等.

关键词: 高温, 水热合成, 有序介孔材料, 二氧化硅, 聚合物

Abstract:

The hydrothermal synthesis of ordered mesoporous materials with high stability at high temperatures is currently a hot topic in the materials field. This review covers recent developments in the synthesis of ordered mesoporous silicas, titanosilicates and polymer materials with high hydrothermal stability at high temperatures. The uses of fluorocarbon and hydrocarbon surfactant mixtures and solo hydrocarbon surfactants are also discussed.

Key words: High temperature, Hydrothermal synthesis, Ordered mesoporous materials, Silica, Polymer

MSC2000: 

  • O643