溅射-置换法制备染料敏化太阳能电池对电极Pt/FTO

doi:10.3866/PKU.WHXB20101026

物理化学学报 >> 2010, Vol. 26 >> Issue (11): 2957-2961.doi: 10.3866/PKU.WHXB20101026

溅射-置换法制备染料敏化太阳能电池对电极Pt/FTO

王耀琼^1,2, 魏子栋^1,2, 蔡洪英¹, 张骞^1,2, 赵巧玲¹

1. 重庆大学化学化工学院, 输配电装备及系统安全与新技术国家重点实验室, 重庆400044;
2. 重庆大学材料科学与工程学院, 重庆400044

收稿日期:2010-05-05 修回日期:2010-06-29 发布日期:2010-10-29
通讯作者: 魏子栋 E-mail:zdwei@cqu.edu.cn
基金资助:
国家自然科学基金(20806096)和重庆大学211 工程三期创新人才培养建设计划研究生开放实验室支持项目(S-09013)资助

Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement

WANG Yao-Qiong^1,2, WEI Zi-Dong^1,2, CAI Hong-Ying¹, ZHANG Qian^1,2, ZHAO Qiao-Ling¹

1. State Key Laboratory of Power Transmission Equipment and System Security and New Technology, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China;
2. School of Material Science and Engineering, Chongqing University, Chongqing 400044, P. R. China

Received:2010-05-05 Revised:2010-06-29 Published:2010-10-29
Contact: WEI Zi-Dong E-mail:zdwei@cqu.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20806096) and Innovative Talent Training Project, Chongqing University, China (S-09013)

摘要/Abstract

摘要：

采用溅射-置换(SD)法在导电玻璃(FTO)基底上制备了染料敏化太阳能电池(DSSC)对电极SD-Pt/FTO.形貌表征显示, 和热解法(PY)所获得的对电极(PY-Pt/FTO)相比, SD 法获得的对电极SD-Pt/FTO 上Pt 颗粒分散性显著改善. 光电流-光电压特性曲线测试表明, 以SD-Pt/FTO 为DSSC 对电极的光电转化效率比以PY-Pt/FTO为DSSC对电极的提高了16.5%. DSSC 电池性能改善与SD-Pt/FTO对电极具有较低的电阻和由Pt 颗粒分散性改善引起催化性能改善密切相关.

关键词: 染料敏化太阳能电池, 电极, 溅射, 铂

Abstract:

APt/FTOelectrode for dye-sensitized solar cells (DSSC) was prepared by the sputtering (Cu) -displacement (Pt) (SD) method on a conductive glass (FTO) substrate (SD-Pt/FTO). Morphological characterization revealed that the dispersion of Pt particles on the SD-Pt/FTO electrode was significantly improved in comparison with the PY-Pt/FTO electrode prepared by the pyrolysis of Pt salts (PY). Optical current-voltage curves showed that the photoelectric conversion efficiency of DSSC with a SD-Pt/FTO counter electrode increased by 16.5% relative to that with a PY-Pt/ FTO counter electrode. The improvement of DSSC performance with the SD-Pt/FTO electrode is due to its lower electric resistance, and good catalysis resulting from the improved dispersion of Pt particles in the SD process compared with the PY process.

Key words: Dye-sensitized solar cell, Electrode, Sputtering, Pt

MSC2000:

O643.36

王耀琼, 魏子栋, 蔡洪英, 张骞, 赵巧玲. 溅射-置换法制备染料敏化太阳能电池对电极Pt/FTO[J]. 物理化学学报, 2010, 26(11): 2957-2961.

WANG Yao-Qiong, WEI Zi-Dong, CAI Hong-Ying, ZHANG Qian, ZHAO Qiao-Ling. Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement[J]. Acta Phys. -Chim. Sin., 2010, 26(11): 2957-2961.

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溅射-置换法制备染料敏化太阳能电池对电极Pt/FTO

Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement

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